Dec 29, 2025 Leave a message

Core Chemical Composition Differences Between Hastelloy Alloys and Monel Alloys

1. Core Matrix Elements

Monel alloys

The core matrix is composed of nickel (Ni) and copper (Cu), with nickel as the primary element (accounting for 60%–70%) and copper as the secondary core element (accounting for 28%–34%). Other trace elements include iron (Fe, ≤2.5%), manganese (Mn, ≤2%), silicon (Si, ≤1%), etc.

The most representative grade is Monel 400, whose chemical composition is dominated by Ni-Cu binary alloy system, without high-content chromium (Cr) or molybdenum (Mo) elements.
Hastelloy alloys

The core matrix is nickel (Ni) (as the base element, accounting for 40%–60%), supplemented by high-content chromium (Cr) and molybdenum (Mo). Different Hastelloy grades are adjusted based on this core system, and some grades also add tungsten (W), iron (Fe), cobalt (Co) and other elements to optimize performance.

For example:

Hastelloy C276: Ni (balance), Cr (14.5%–16.5%), Mo (15.0%–17.0%), W (3.0%–4.5%), Fe (4.0%–7.0%).

Hastelloy B2: Ni (balance), Mo (26.0%–30.0%), Fe (≤2.0%), Cr (≤1.0%).

2. Key Differentiating Elements

The essential chemical difference between the two alloy series lies in the presence of high-content Cr and Mo in Hastelloy alloys and their absence in Monel alloys.

Monel alloys rely on the Ni-Cu binary system to achieve corrosion resistance, especially in seawater, hydrofluoric acid and other media.

Hastelloy alloys rely on the synergistic effect of Cr, Mo and W to form a dense passivation film on the surface, thus obtaining excellent corrosion resistance to strong oxidizing media, reducing media and mixed acids, which is far superior to Monel alloys in harsh corrosive environments.

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3. Summary of Core Differences

Characteristic Monel Alloys Hastelloy Alloys
Core Matrix System Ni-Cu binary alloy Ni-Cr-Mo ternary alloy (or Ni-Cr-Mo-W quaternary alloy)
Core Differentiating Elements No high-content Cr/Mo High-content Cr & Mo (with W added in some grades)
Trace Elements Fe, Mn, Si (low content) Fe, Co, W (adjusted by grade)

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